She should use fractional distillation to separate ethanol from water.

Why fractional distillation?

  • Ethanol and water are both liquids that mix completely, so methods like filtration or decanting will not work.
  • They have different boiling points (ethanol around 78 °C, water around 100 °C), so heating the mixture and condensing the more volatile component (ethanol) allows separation.
  • A fractional distillation setup (flask, fractionating column, condenser) lets ethanol vapor rise and condense first, giving a purer ethanol sample than simple distillation.

In many school‑level chemistry questions with this exact wording about ethanol and water, “fractional distillation” is the expected one‑line answer.

TL;DR: Janine should use fractional distillation, taking advantage of the different boiling points of ethanol and water.

Information gathered from public forums or data available on the internet and portrayed here.